DISCUSSION/IN PRESS/ACCEPTED
(61) Kolesar, K. R.; Buffaloe, G. M.; Wilson, K. R.; Cappa, C. D.; “OH-initiated Heterogeneous Oxidation of Internally-Mixed Squalane and Secondary Organic Aerosol.” Environ. Sci. Technol., Accepted.
PUBLISHED
2014
(60) Buffaloe, G. M.; Lack, D. A.; Williams, E. J.; Coffman, D.; Hayden, K. L.; Lerner, B. M.; Li, S-M.; Nuaaman I.; Massoli, P.; Onasch, T. B.; Quinn, P. K.; Cappa, C. D.; “Black carbon emissions from in-use ships: a California regional assessment.” Atmos. Chem. Phys., 2014, 14, 1881-1896, DOI: 10.5194/acp-14-1881-2014. (link)
(59) Cappa, C. D.; Lack, D. A.; Williams, Buffaloe, G. M.; E. J.; Coffman, D.; Hayden, Herndon, S. C.; K. L.; Lerner, B. M.; Li, S-M.; McLaren, R.; Massoli, P.; Nuaaman I.; Onasch, T. B.; Quinn, P. K.; “A case study into the measurement of ship emissions from plume intercepts of the NOAA Ship Miller Freeman.” Atmos. Chem. Phys., 2014, 14, 1337-1352, DOI: 10.5194/acp-14-1337-2014. (link)
2013
(58) Forestieri, S. D.; Collier, S.; Kuwayama, T.; Zhang, Q.; Kleeman, M. J.; Cappa, C. D.; “Real-time black carbon emission factor measurements from light duty vehicles.” Environ. Sci. Technol., 2013, 47 (22), 13104–13112, DOI: 10.1021/es401415a. (link)
(57) Lambe, A.; Cappa, C. D.; Massoli, P.; Onasch, T. B.; Forestieri, S.; Martin, A.; Cummings, M.; Croasdale, D.; Brune, B.; Worsnop, D.; Davidovits, P.; “Relationship between oxidation level and optical properties of secondary organic aerosols.” Environ. Sci. Technol., 2013, 47, 6349-6357, DOI: 10.1021/es401043j. (link)
(56) Harmon, C. W.; Ruehl, C. R.; Che, D.; Smith, J. D.; Cappa, C. D.; Wilson, K. R. “A Statistical Description of the Evolution of Cloud Condensation Nuclei Activity during the Heterogeneous Oxidation of Squalane and Bis(2-ethylhexyl) Sebacate Aerosol by Hydroxyl Radicals.” Phys. Chem. Chem. Phys., 2013, 15, 9679-9693, DOI: 10.1039/C3CP50347J. (link)
(55) Ruehl, C.; Nah, T.; Isaacman, G.; Worton, D.; Chan, A.; Kolesar, K.; Cappa, C. D.; Goldstein, A.; Wilson, K. R.; “The Influence of Molecular Structure and Aerosol Phase on the Heterogeneous Oxidation of Normal and Branched Alkanes by OH.” J. Phys. Chem. A., 2013, 117 (19), 3990-4000, DOI: 10.1021/jp401888q. (link)
(54) Prather, K.A.; Bertram, T. H.; Grassian, V.H.; Deane, G.B.; Stokes, M. D.; DeMott, P. J.; Aluwihare, L. I.; Palenik, B.; Azam, F.; Seinfeld, J. H.; Moffet, R. C.; Molina, M. J.; Cappa, C. D.; Geiger, F. M.; Roberts, G. C.; Russell, L. M.; Ault, A. P.; Baltrusaitis, J.; Collins, D. B.; Corrigan, C. E.; Cuadra-Rodriguez, L. A.; Ebben, C. J.; Forestieri, S. D.; Guasco, T. L.; Hersey, S. P.; Kim, M. J.; Lambert, W.; Modini, R. L.; Mui, W.; Pedler, B. E.; Ruppel, M. J.; Ryder, O. S.; Schoepp, N.; Sullivan, R. C.; Zhao, D.; “Bringing the ocean into the laboratory: Impacts of chemical complexity of sea spray aerosol on climate properties.” Proceedings of the National Academy of Science, 2013, 110 (19), 7550-7555. DOI: 10.1073/pnas.1300262110. (link) Coverage: UCD Aggie, Scientific American
(53) Farmer, D. K., Chen, Q., Kimmel, J. R., Docherty, K. S., Nemitz, E., Artaxo, P. A., Cappa, C. D., Martin, S. T., Jimenez, J. L.; “Chemically-resolved particle fluxes over tropical and temperate forests.” Aerosol Science and Technology, 2013, 47, 818-830, DOI: 10.1080/02786826.2013.791022. (link)
(52) Cappa, C.D.; Lovejoy, E.R.; Ravishankara, A.R.; “Correction to: Evaporation rates and vapor pressures of the even-numbered C8-C18 monocarboxylic Acids.” J. Phys. Chem. A., 2013, DOI: 10.1021/jp4017213. Correction to Table 1 (link) (pdf).
(51) Cappa, C. D.; Zhang, X.; Loza, C. L.; Craven, J. S.; Yee, L. D.; Seinfeld, J. S.; “Application of the Statistical Oxidation Model (SOM) to secondary organic aerosol formation from photooxidation of C12 Alkanes.” Atmospheric Chemistry and Physics, 2013, 13, 1591-1606. (pdf) (link)
(50) Cappa, C. D.; Onasch, T. B.; Massoli, P.; Worsnop, D.; Bates, T. S.; Cross, E.; Davidovits, P.; Hakala, J.; Hayden, K.; Jobson, B. T.; Kolesar, K. R.; Lack, D. A.; Lerner, B.; Li, S. M.; Mellon, D.; Nuaanman, I.; Olfert, J.; Petaja, T.; Quinn, P. K.; Song, C.; Subramanian, R.; Williams, E. J.; and Zaveri, R. A.; “Response to Comment on ‘Radiative absorption enhancements due to the mixing state of atmospheric black carbon’.” Science, 2013, 339, 393-c, doi: 10.1126/science.1230260. (link to our response) (link to comment by Jacobson)
2012
(49) Ruehl, C. R.; Chuang, P. Y.; Nenes, A.; Cappa, C. D.; Kolesar, K. R.; Goldstein, A. H.; “Strong evidence of surface tension reduction in microscopic aqueous droplets.” Geophys. Res. Lett., 2012, 39, L23801, doi:10.1029/2012GL053706. (link)
(48) Cappa, C. D. and Wilson, K. R.; “Multi-generation gas-phase oxidation, equilibrium partitioning and the formation and evolution of secondary organic aerosol.” Atmospheric Chemistry and Physics, 2012, 12, 9505-9528, doi:10.5194/acp-12-9505-2012. (link)
(47) Cappa, C. D.; Onasch, T. B.; Massoli, P.; Worsnop, D.; Bates, T. S.; Cross, E.; Davidovits, P.; Hakala, J.; Hayden, K.; Jobson, B. T.; Kolesar, K. R.; Lack, D. A.; Lerner, B.; Li, S. M.; Mellon, D.; Nuaanman, I.; Olfert, J.; Petaja, T.; Quinn, P. K.; Song, C.; Subramanian, R.; Williams, E. J.; and Zaveri, R. A.; “Radiative absorption enhancements due to the mixing state of atmospheric black carbon.” Science, 2012, 337, 1078-1081, doi: 10.1126/science.1223447. (link) (Supplementary Material) Coverage: (C&E News, Science Daily, Futurity, Boston Globe,NYTimes)
(46) Lack, D.A.; Langridge, J.M.; Bahreini, R.; Cappa, C.D.; Middlebrook, A.M; Schwarz, J.P.; “Brown carbon and internal mixing in biomass burning particles.” Proceedings of the National Academy of Science, 2012, 109(37), 14802-14807, doi: 10.1073/pnas.1206575109. (link)
(45) Zaveri et al.; “ Overview of the 2010 Carbonaceous Aerosols and Radiative Effects Study.” Atmospheric Chemistry and Physics, 2012, 12, 7647-7687, doi:10.5194/acp-12-7647-2012. (link)
(44) Bates, T.S.; Quinn, P.K. Frossard, A.A.; Russell, L.M.; Hakala, J.; Petaja, T.; Kulmala, M.; Covert, D.S.; Cappa, C.D.; Li, S-M.; Hayden, K.L.; Nuaaman, I.; McLaren, R.; Massoli, P.; Canagaratna, M.R.; Onasch, T.B.; Sueper, D.; Worsnop, D.R.; Keene, W.C.; “Measurements of ocean derived aerosol off the coast of California.” Journal of Geophysical Research, 2012, 117, D00V15, doi:10.1029/2012JD017588. (link)
(43) Lack, D.A.; Richardson, M.S.; Law, D.; Langridge, J.M.; Cappa, C.D.; Murphy, D.M.; “Aircraft instrument for comprehensive characterization of aerosol optical properties, Part 2: Black and brown carbon absorption and absorption enhancement measured with photo-acoustic spectroscopy.” Aerosol Science and Technology, 2012, 46(5), 555-568, doi:10.1080/02786826.2011.645955. (link)
2011
(42) Lack, D.A.; Cappa, C.D.; Langridge, J.; et al.; “Impact of Fuel Quality Regulation and Speed Reductions on Shipping Emissions: Implications for Climate and Air Quality.” Environmental Science and Technology, 2011, 45 (20), pp 9052–9060, doi: 10.1021/es2013424 (link/pdf).
(41) Cappa, C.D.; Che, D.L.; Kessler, S.H.; Kroll, J.H.; Wilson, K.R.; “Variations in organic aerosol optical and hygroscopic properties upon heterogeneous OH oxidation.” Journal of Geophysical Research, 2011, 116, D15204, doi:10.1029/2011JD015918 (pdf) (link).
(40) Cappa, C.D. and Wilson, K.R.; “Evolution of organic aerosol mass spectra upon heating: Implications for OA phase and partitioning behavior.” 2011, Atmospheric Chemistry and Physics,11, 1895-2011. (pdf)
(39) Dzepina, K.; Cappa, C.D.; Volkamer, R.M.; Madronich, S.; DeCarlo, P.F.; Zaveri, R.A.; and Jimenez, J.L.; “Modeling the Multiday Evolution and Aging of Secondary Organic Aerosol During MILAGRO 2006.” Environmental Science and Technology, 2011, 45(8), 3496-3503, doi: 10.1021/es103186f. (link)
(38) Diaz-Valbuena, L.R.; Leverenz, H.L.; Cappa, C.D.; Tchobanoglous, G.; Horwath, W.R.; Darby, J.L.; “Methane, Carbon Dioxide, and Nitrous Oxide Emissions from Septic Tank Systems.”Environmental Science and Technology, 2011, 45(7), 2741-2747, doi: 10.1021/es1036095. (link); See also: feature in C&E News Environmental Scene (link)
2010
(37) Cross, E.S.; Onasch, T.B.; Ahern, A.; Wrobel, W.; Slowik, J.G.; Olfert, J.; Lack, D.A.; Massoli, P.; Cappa, C.D.; Schwarz, J.; Spackman, R.; Fahey, D.W.; Sedlacek, A.; Trimborn, A.; Jayne, J.T.; Freedman, A.; Williams, L.R.; Ng, N.L.; Mazzoleni, C.; Dubey, M.; Brem, B.; Kok, G.; Subramanian, R.; Freitag, S.; Clarke, A.; Thornhill, D.; Marr, L.; Kolb, C.E.; Worsnop, D.R.; Davidovits, P.; “Soot Particle Studies – Instrument Intercomparison – Project Overview.” Aerosol Science and Technology, 2010, 44(8), 592-611, doi: 10.1080/02786826.2010.482113. (pdf) (link)
(36) Clark, G.N.I.; Cappa, C.D.; Smith, J.D.; Saykally, R.J.; Head-Gordon, T.; “The structure of ambient water.” Molecular Physics, 2010, 11, 1415-1433. (Invited Review Article) (pdf)
(35) Cappa, C.D.; Jimenez, J.L.; “Quantitative estimates of the volatility of ambient organic aerosol.” Atmospheric Chemistry and Physics, 2010, 10, 5409-5424. (link)
(34) Cappa, C.D.; “A Model of Aerosol Evaporation Kinetics in a Thermodenuder.” Atmospheric Measurement Techniques , 2010, 3, 579-592. (link)
(33) Lack, D.A.; Cappa, C.D.; “Impact of Brown and Clear Carbon on Light Absorption Enhancement, Single Scatter Albedo and Absorption Wavelength Dependence of Black Carbon.”Atmospheric Chemistry and Physics, 2010, 10, 4207-4220. (link)
2009
(32) Cappa, C.D.; Bates, T.S.; Quinn, P.K.; Lack, D.A.; “Source Characterization from Ambient Measurements of Aerosol Optical Properties.” Geophysical Research Letters, 2009, 36, L14813, doi:10.1029/2009GL038979. (link)
(31) Lack, D.A.; Cappa, C.D.; Cross, E.S.; Massoli, P.; Ahern, A.T.;Davidovits, P.; Onasch, T.B.; “Absorption Enhancement of Coated Absorbing Aerosols: Validation of the Photo-acoustic Technique for Measuring the Enhancement.” Aerosol Science and Technology, 2009, 43(10), 1006-1012. (pdf) (link)
(30) Dzepina, K.; Volkamer, R.; Madronich, S.; Tulet, P.; Ulbrich, I.; Zhang, Q.; Cappa, C.D.; Ziemann, P.J.; Jimenez, J.L.; “Evaluation of New Secondary Aerosol Models for a Case Study in Mexico.” Atmospheric Chemistry and Physics, 2009, 9, 5681-5709. (link)
(29) Smith, J.D.; Kroll, J.H.; Cappa, C.D.; Che, D.L.; Ahmed, M.; Leone, S.R.; Worsnop, D.R.; Wilson, K.R.; “The Heterogeneous Reaction of sub-micron Squalane Particles with OH Radicals: A Model System for Understanding the Oxidative Aging of Ambient Aerosols.” Atmospheric Chemistry and Physics, 2009, 9, 3209-322. (pdf) (link)
2008
(28) Cappa, C.D.; Lovejoy, E.R.; Ravishankara, A.R.; “Evaporation and Non-Ideal Behavior of Multi-Component Organic Mixtures.” Proceedings of the National Academy of Sciences, 2008,105, 18687-18691. (pdf) (link)
(27) Drisdell, W.S.; Smith, J.D.; Cappa, C.D.; Cohen, R.C.; Saykally, R.J.; “Determination of the Evaporation Coefficient of Liquid D2O via Raman Thermometry of Freely Evaporating Droplet Trains.” Atmospheric Chemistry and Physics, 2008, 8, 6699-6706. (pdf)
(26) Lack, D.A.; Cappa, C.D.; Baynard, T.; Massoli, P.; Covert, D.; Sierau, B.; Bates, T.; Quinn, T.; Lovejoy, E.R.; Ravhishankara, A.R.; “Bias in filter based aerosol light absorption measurements due to organic aerosol loading: Evidence from ambient sampling.” Aerosol Science and Technology, 2008, 42(12), 1033-1041. (pdf) ** One of the 10 most cited articles of 2009 from AS&T.
(25) Cappa, C.D.; Lack, D.A; Burkholder, J.B.; Ravishankara, A.R.; “Bias in filter based aerosol light absorption measurements due to organic aerosol loading: Evidence from laboratory measurements.” Aerosol Science and Technology, 2008, 42(12), 1022-1032. (pdf)
(24) Cappa, C.D.; Smith, J.D.; Wilson, K.R.; Saykally, R.J.; “Revisiting the Total Ion Yield X-ray Absorption Spectra of Liquid Water Microjets.” J. Phys. Cond. Matt., 2008, 20(20), Art. No. 205105. (pdf)
(23) Cappa, C.D.; Lovejoy, E.R.; Ravishankara, A.R.; “Evaporation rates and vapor pressures of the even-numbered C8-C18 monocarboxylic Acids.” J. Phys. Chem. A., 2008, 112(17), 3959. (pdf) (link). Correction to Table 1 (link) (pdf).
2007
(22) Cappa, C.D.; Lovejoy, E.R.; Ravishankara, A.R.; “Determination of evaporation rates and vapor pressures of very low volatility compounds: a study of the C4-C10 and C12 dicarboxylic acids.” J. Phys. Chem. A, 2007, 111(16), 3099. (pdf) (link)
(21) *Cappa, C.D.; Smith, J.D.; Messer, B.M.; Cohen, R.C.; Saykally, R.J.; “Nature of the aqueous hydroxide ion probed by X-ray absorption spectroscopy.” J. Phys. Chem. A., 2007, 111(22), 4776. (pdf) (link)
(20) Cappa, C.D.; Smith, J.D.; Drisdell, W.S.; Saykally, R.J.; Cohen, R.C.; “Interpreting the H/D isotope fractionation of water during evaporation without condensation.” J. Phys. Chem. C.,2007, 111(19), 7011. (pdf)
2006
(19) Smith, J.D.; Cappa, C.D.; Messer, B.M.; Drisdell, W.S.; Cohen, R.C.; Saykally, R.J.; “Probing the local structure of liquid water using x-ray absorption spectroscopy.” J. Phys. Chem. B.,2006, 110(40), 20038. (pdf)
(18) Smith, J.D.; Cappa, C.D.; Drisdell, W.S.; Wilson, K.R.; Cohen, R.C.; Saykally, R.J.; “Raman thermometry measurements of free evaporation from liquid water droplets.” J. Am. Chem. Soc., 2006, 128(39), 12892. (pdf) (link)
(17) Cappa, C.D.; Smith, J.D.; Messer, B.M.; Cohen, R.C.; Saykally, R.J.; “Effects of cations on the hydrogen bond network of liquid water: New results from X-ray absorption spectroscopy of liquid microjets.” J. Phys. Chem. B, 2006, 110, 5301. (pdf)
(16) Cappa, C.D.; Smith, J.D.; Messer, B.M.; Cohen, R.C.; Saykally, R.J.; “The electronic structure of the hydrated proton: a comparative X-ray absorption study of aqueous HCl and NaCl solutions.” J. Phys. Chem. B, 2006, 110, 1166. (pdf)
2005
(15) Cappa, C.D.; Drisdell, W.S.; Smith, J.D.; Saykally, R.J.; Cohen, R.C.; “Isotope fractionation of water during evaporation without condensation.” J. Phys. Chem. B, 2005, 109(51), 24391.(pdf)
(14) Messer, B.M.; Cappa, C.D.; Smith, J.D.; Drisdell, W.S.; Schwartz, C.P.; Cohen, R.C.; Saykally, R.J.; “Local hydration environments of amino acids and dipeptides studied by x-ray spectroscopy of liquid microjets.” J. Phys. Chem. B, 2005, 109(46), 21640. (pdf)
(13) Smith, J.D.; Cappa, C.D.; Wilson, K.R.; Cohen, R.C.; Geissler, P.L.; Saykally, R.J.; “Unified description of temperature-dependent hydrogen-bond rearrangements in liquid water.” PNAS,2005, 102(40), 14171. (pdf)
(12) Smith, J.D.; Cappa, C.D.; Messer, B.M.; Cohen R.C. and Saykally, R.J.; Response to Comment on “Energetics of hydrogen bond network rearrangements in liquid water.” Science, 2005,308(5723), 793. (pdf)
(11) *Cappa, C.D.; Smith, J.D.; Wilson, K.R.; Messer, B.M.; Gilles, M.K.; Cohen, R.C.; Saykally, R.J.; “Effects of alkali metal halide salts on the hydrogen bond network of liquid water.” J. Phys. Chem. B, 2005, 109(15), 7046. (pdf)
(10) *Messer, B.M.; Cappa, C.D.; Smith, J.D.; Wilson, K.R.; Gilles, M.K.; Cohen, R.C.; Saykally, R.J.; “pH dependence of the electronic structure of Glycine.” J. Phys. Chem.. B, 2005,109(11), 5375. (pdf)
2004
(9) Smith, J.D.; Cappa, C.D.; Wilson, K.R.; Messer, B.M.; Cohen, R.C.; Saykally, R.J.; “Energetics of hydrogen bond network rearrangement in liquid water.” Science, 2004, 306, 851. (pdf) (link)
(8) Angert, A.; Cappa, C.D.; DePaolo, D.J., “Kinetic 17O effects in the hydrologic cycle: Indirect evidence and implications.” Geochim. Cosmochim. Acta, 2004, 68, 3441. (pdf)
(7) Cappa, C.D.; Wilson, K.R.; Messer, B.M.; Saykally, R.J.; Cohen R.C.; “Optical cavity resonances in water micro-droplets: Implications for shortwave cloud forcing.” Geophys. Res. Lett.,2004, 31, L1025, doi:10.1029/2004GL019593. (pdf)
(6) Wilson, K.R.; Rude, B.S.; Smith, J.D.; Cappa, C.D.; Co, D.T.; Schaller, R.D.; Larsson, M.; Catalano, T.; Saykally, R.J.; “Investigation of volatile liquid surfaces by synchrotron x-ray spectroscopy of liquid microjets.” Rev. Sci. Inst., 2004, 75(3), 725. (pdf)
2003 and earlier
(5) Cappa, C.D.; Hendricks, M.B.; DePaolo, D.J.; Cohen, R.C., “Isotopic fractionation of water during evaporation.” J. Geophys. Res., 2003, 108(D16), Art.No. 4525. (pdf)
(4) Cappa, C. D. and M. J. Elrod, “A computational investigation of the electron affinity of CO3 and the thermodynamic feasibility of CO3–(H2O)n + ROOH reactions” Phys. Chem. Chem. Phys.,2001, 3, 2986. (pdf)
(3) Cappa, C.D.; Kuipers, S.E.; Roberts, J.M.; Gilbert, A.S.; Elrod, M.J. “Product identification and kinetics of reactions of HCl with HNO3/H2SO4/H2O solutions.” J. Phys. Chem. A, 2000,104, 4449. (pdf)
(2) Messer, B. M.; Stielstra, D.E.; Cappa, C.D.; Scholtens, K.W.; Elrod, M. J. “Computational and experimental studies of chemical ionization mass spectrometric techniques for atmospherically relevant peroxides.” Int. J. Mass Spectrom., 2000, 197, 219. (pdf)
(1) Scholtens, K.W.; Messer, B.M.; Cappa, C.D.; Elrod, M.J. “Kinetics of the CH3O2 + NO reaction: Temperature dependence of the overall rate constant and an improved upper limit for the CH3ONO2 branching channel.” J. Phys. Chem. A, 1999, 103(22), 4378. (pdf)
*Cover article